BETHESDA, Md.—Anthony Kim finally gets a crack at Tiger Woods, and when he says he has been practicing for a moment like this all his life, Kim isn’t kidding.

As a 10-year-old growing up in Los Angeles, in those final hours of twilight as he waited for his father to pick up from the golf course, Kim imagined he was in the final pairing with Woods and had a 10-foot putt for the victory, with the world’s No. 1 player watching.

“Man, they were going in a lot,” Kim said, laughing.

He can only hope fantasy meets reality Sunday in the AT&T National.

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